Unraveling the Silent Menace - Galvanic Corrosion

23 May 2024
Understanding galvanic corrosion
Understanding galvanic corrosion
Government of Canada, Canadian Conservation Institute. CCI 129916-0021
Understanding galvanic corrosion - Canada.ca

Introduction

Back in the 1800s, amidst the age of industrial revolution, the realms of science and innovation were ablaze with discovery. Two luminaries, Luigi Galvani and Alessandro Volta, found themselves at the forefront of this intellectual ferment. As they delved into the mysteries of metals and electricity, their experimentation yielded a curious revelation: the phenomenon of galvanic corrosion. When disparate metals were immersed in water, a subtle but transformative process ensued – corrosion. Galvani's name was forever enshrined in scientific lore as the duo christened this phenomenon "galvanic corrosion" in his honor.

This serendipitous discovery set in motion a journey of exploration, as scientists and engineers sought to unravel the intricate mechanisms governing the interaction between metals and electrical currents. From the laboratories of the 19th century to the bustling industries of the modern era, galvanic corrosion has emerged as a formidable challenge in sectors ranging from construction to transportation. With each passing decade, our understanding of this phenomenon deepened, paving the way for innovative solutions and preventive measures.

The story of galvanic corrosion is not merely a historical footnote but a testament to the enduring spirit of human inquiry and ingenuity. It serves as a poignant reminder that even the most inconspicuous discoveries can catalyze profound advancements, shaping the course of industries and society at large. Today, as we navigate the complexities of modern engineering, the legacy of Galvani and Volta's pioneering work continues to illuminate our path forward, underscoring the transformative power of curiosity and innovation.

What is Galvanic Corrosion

Galvanic corrosion, also known as bimetallic corrosion, is an electrochemical process wherein one metal corrodes preferentially over another metal when they are in contact through an electrolyte. This occurs when dissimilar metals are submerged in a conductive solution and electrically connected. During this process, one metal acts as the cathode and remains protected, while the other metal serves as the anode and corrodes. Over time, the corrosion of the anode accelerates.

For instance, if aluminum and carbon steel are immersed in a conductive solution and an electrical connection is established, aluminum will corrode at a faster rate compared to carbon steel. In this scenario, carbon steel receives protection while aluminum undergoes corrosion.
To know more about Identifying Fastener Corrosion and How to Prevent It click here.

Galvanic Corrosion on a Steel Bolt and Nut
Galvanic Corrosion on a Steel Bolt and Nut
ThePipingMart Blog (2021, October 6th). What Is Galvanic Corrosion.
https://blog.thepipingmart.com/other/what-is-galvanic-corrosion/

Types of Galvanic Corrosion

1. Galvanic Corrosion in Plumbing Systems

In household plumbing systems, the occurrence of galvanic corrosion when copper pipes are connected to steel fittings is a common concern. The process is facilitated by the flow of water through the pipes, which acts as an electrolyte, enabling an electrochemical reaction between the dissimilar metals.

As the water serves as a conductor, electrons flow between the copper pipes (acting as the cathode) and the steel fittings (acting as the anode), accelerating the corrosion process. Over time, this corrosion can manifest in various forms, including pitting, scaling, or even the formation of leaks at the connection points.

Not only does this compromise the structural integrity of the plumbing system, but it can also lead to water damage, mold growth, and potentially costly repairs. To prevent galvanic corrosion in household plumbing, it is essential to use compatible metals, employ dielectric fittings or insulating materials, and regularly inspect and maintain the system to address any signs of corrosion promptly. By implementing these preventive measures, homeowners can ensure the longevity and reliability of their plumbing infrastructure.

Galvanic Corrosion on plumbing systems
Galvanic Corrosion on plumbing systems
Fred S. (2012, August 1st). Galvanic Corrosion in Long Beach older homes plumbing systems.
https://activerain.com/blogsview/3395087/galvanic-corrosion-in-long-beach-older-homes-plumbing-systems-

2. Galvanic Corrosion in Automotive Applications

In the intricate ecosystem of an automobile, the interaction of various metals can set the stage for galvanic corrosion, a potentially destructive force. As cars traverse roads, they face exposure to a myriad of environmental factors, including moisture from rain and the corrosive effects of road salt used during winter months.

When metals such as steel, aluminum, and zinc-coated steel (galvanized steel) coexist within the vehicle's structure, these disparate materials can initiate an electrochemical reaction when in contact, particularly in the presence of water or electrolytes.

This reaction accelerates corrosion on the less noble metal, often resulting in rust formation on vulnerable components like body panels, chassis parts, and fasteners. Beyond mere aesthetic concerns, the consequences of galvanic corrosion can compromise the structural integrity and safety of the vehicle.

Rust weakening critical components like chassis frames or compromising fasteners can lead to catastrophic failures, jeopardizing not only the vehicle occupants but also those sharing the road. To mitigate the risk of galvanic corrosion, automobile manufacturers employ various strategies, including material selection, corrosion-resistant coatings, and design considerations to minimize metal-to-metal contact.

Furthermore, regular maintenance, such as washing away road salt residue and promptly addressing any signs of corrosion, is imperative for preserving the durability and safety of modern vehicles in the face of this silent adversary.

Galvanic Corrosion on a car 1
SGalvanic Corrosion on a car 2
Galvanic Corrosion on a car

3. Galvanic Corrosion in Rooftops Installation

When stainless steel self-drilling roof screws are utilized to secure Color bond painted steel roof sheeting, the potential for galvanic corrosion arises due to the interaction between dissimilar metals. Stainless steel inherently resists corrosion, while Color bond steel is coated with a zinc-aluminum alloy and painted for added protection and aesthetics. However, when these materials interact, especially in the presence of moisture or electrolytes like rainwater, galvanic corrosion may occur.

Galvanic corrosion is an electrochemical process where the more noble metal (stainless steel) acts as the cathode and the less noble metal (Color bond steel) becomes the anode. This leads to accelerated corrosion of the anodic metal (Color bond steel), compromising its structural integrity over time. The risk is further heightened if protective coatings on either material are imperfect or damaged, allowing direct metal-to-metal contact and facilitating the corrosion process.

To mitigate this risk, careful selection of fasteners and materials that are compatible with each other is essential. It's advisable to avoid using stainless steel fasteners with Color bond steel roofing to minimize the risk of galvanic corrosion, as their dissimilar materials can lead to potential issues. Additionally, ensuring proper installation techniques, such as sealing potential points of contact between dissimilar metals and maintaining the integrity of protective coatings, can help mitigate the risk of galvanic corrosion and extend the lifespan of the roofing system. Regular inspections and maintenance practices can also aid in identifying and addressing any corrosion issues promptly, preserving the structural integrity and aesthetics of the roofing installation over time.

Galvanic corrosion on rooftops presents a multifaceted challenge due to the diverse range of metals utilized in their construction. As rainwater cascades down and moisture lingers, it creates an environment ripe for electrochemical reactions between these dissimilar metals. Each metal, with its unique composition, unwittingly participates in this silent battle, wherein one metal sacrifices itself for the corrosion of the other. This ongoing process accelerates the deterioration of rooftop materials, compromising not only their structural integrity but also their overall longevity.

Whether it is steel fasteners joining aluminum panels or copper flashing in contact with galvanized steel gutters, the potential for galvanic corrosion to silently eat away at rooftop elements is a constant concern. This underscores the critical importance of meticulous material selection and the implementation of preventive measures to fortify rooftops against this concealed menace. By carefully considering the compatibility of metals and employing protective coatings or insulating materials, property owners can safeguard their rooftops, ensuring they remain durable and resilient against the insidious effects of galvanic corrosion for years to come.

Ambrose Construct Group (2017, August 28th). Dissimilar Metal Roof Sheeting – Galvanic Corrosion.
Ambrose Construct Group (2017, August 28th). Dissimilar Metal Roof Sheeting – Galvanic Corrosion.
Dissimilar Metal Roof Sheeting - Galvanic Corrosion - Ambrose Construct Group (ambrosebuilding.com.au)
Vantage Point Roofing (2018, June 13th). Common Roofing Issues 2: Galvanic Corrosion, Leaks, Mould & Watermarks.
Vantage Point Roofing (2018, June 13th). Common Roofing Issues 2: Galvanic Corrosion, Leaks, Mould & Watermarks.
COMMON ROOFING ISSUES 2: Galvanic Corrosion, Leaks, Mould & Watermarks (vantagepointroofing.com.au)

4. Galvanic Corrosion on Fastener, Bolts & Nuts

Galvanic corrosion quietly poses a significant threat, especially for fasteners like bolts and nuts used in various construction applications. When dissimilar metals, such as steel and aluminum, come into contact, particularly in environments rich in moisture or electrolytes like saltwater, galvanic corrosion can swiftly take hold. This electrochemical process accelerates the corrosion of the more reactive metal, compromising the integrity of the fastening mechanism.

For instance, when a steel bolt secures an aluminum component, the aluminum, being less noble, is susceptible to faster corrosion, potentially weakening or causing failure in the connection over time. Improper fastener selection exacerbates this risk, such as using galvanized carbon steel bolts with stainless steel components, accelerating corrosion rates and leading to eventual structural failure.

Overlooking the need for electrical insulation between dissimilar metals, like copper and aluminum, further heightens galvanic corrosion risks, jeopardizing the longevity of roofing and cladding systems. Even minor oversights, like missing inert washers or insufficient protective coatings, inadvertently foster electrical contact between metals, amplifying corrosion effects. To counter this risk, meticulous consideration in selecting materials for fasteners and applying appropriate coatings is crucial.

Choosing compatible metals or employing protective coatings like zinc plating or galvanization significantly reduces the likelihood of galvanic corrosion. Moreover, during construction or maintenance, proactive steps must be taken to minimize metal-to-metal contact between dissimilar materials, effectively mitigating the potential for galvanic corrosion to occur. These preventive measures play a pivotal role in preserving the durability and reliability of fasteners in critical structural applications, ensuring the ongoing safety and stability of constructed environments.

Galvanic Corrosion on a fastener
Galvanic Corrosion on a fastener

Ways to prevent Galvanic Corrosion

Preventing galvanic corrosion is paramount for maintaining the strength and durability of metal structures. Several strategies can be employed to mitigate the risk of galvanic corrosion and prolong the lifespan of these structures.

Firstly, selecting materials with similar corrosion potentials is a fundamental approach. This minimizes the potential for electrochemical reactions between dissimilar metals, reducing the likelihood of galvanic corrosion. Additionally, employing insulation or spacers to physically separate metals can effectively prevent direct contact, thereby inhibiting the initiation of corrosion.

While applying protective coatings to metal surfaces is a crucial measure, it is important to note that coatings alone may not offer a sustainable solution for eliminating galvanic corrosion. An alternative to consider is using an EPDM washer, which acts as a barrier between the fastener and the substrate, depending on the installation conditions of the washer.
To know more about EPDM washer, click here.

Moreover, incorporating corrosion inhibitors into the environment can further slowdown the chemical reactions that drive galvanic corrosion. These inhibitors work by either forming a protective film on the metal surface or altering the electrolyte composition to make it less corrosive.

By implementing these preventive measures, metal components can be safeguarded against the detrimental effects of galvanic corrosion, ensuring their longevity and structural integrity. Whether in industrial settings, maritime environments, or everyday applications, these simple yet effective strategies play a crucial role in preserving the functionality and safety of metal structures over time.

Your Solution to Corroded Fasteners:

The solution to corroded fasteners varies depending on the extent of corrosion and the specific application. In many cases, cleaning the surface corrosion through methods like wire brushing or chemical treatments. However, it could take up plenty of man hours for your business or projects. The most effective and sustainable way would be to invest in protective coatings that prevent further corrosion. For severe cases, replacing fasteners with corrosion-resistant materials or coated options may be necessary.

Here at Engineering Edge Singapore, we provide CORROSHIELD® fasteners that are designed to withstand harsh environments without corroding. Download our CORROSHIELD® brochure here. Our innovative coatings also cater to various conditions, ensuring long-lasting performance. Take a look at our coating guide here. Additionally, our fasteners undergo rigorous testing, including Salt Spray Tests, to validate their durability.

The Salt Spray Test simulates a harsh and corrosive environment. It replicates the harsh conditions of saltwater exposure over time. The fasteners are placed inside a chamber where a salt solution is sprayed onto its surface, creating a corrosive atmosphere. This test aims to evaluate the fastener's resistance to corrosion by simulating the effects of saltwater, which is known to accelerate corrosion processes. Over the testing period, which can vary depending on standards and requirements, the fastener's performance is closely monitored to assess its durability and suitability for use in corrosive environments.

Visit our blog to learn more about the Salt Spray Test. Additionally, we conduct various other tests to guarantee the durability and quality of our fasteners. Read more on Blog Testing Fastener's Durability here.

CORROSHIELD®: Your solution to Corrosion
CORROSHIELD®: Your solution to Corrosion
Conclusion:

Preventing galvanic corrosion is not just a matter of maintenance; it is an investment in the longevity and reliability of metal structures. Each preventive measure serves as a layer of defense against the insidious effects of galvanic corrosion, which can compromise the integrity of metal components over time.

Choosing materials with similar corrosion potentials is the first line of defence, ensuring that metals in contact are less likely to engage in electrochemical reactions. This simple yet crucial step minimizes the risk of corrosion initiation. However, in situations where dissimilar metals must interact, insulation or spacers act as physical barriers, preventing direct contact and thwarting corrosion at its source.

Protective coatings play a pivotal role in shielding metal surfaces from the corrosive elements present in their environment. These coatings not only provide a barrier against moisture and electrolytes but also ensure that any breaches are swiftly repaired to maintain their effectiveness. Additionally, sacrificial anodes sacrificially corrode to protect primary metal structures, effectively diverting corrosion away from critical components and extending their service life.

Incorporating corrosion inhibitors into the environment further enhances protection by slowing down the chemical reactions responsible for galvanic corrosion. Whether forming a protective film on metal surfaces or altering the electrolyte composition to mitigate corrosion, corrosion inhibitors add an extra layer of defence against corrosion.

While galvanic corrosion may initially seem like a minor concern, its cumulative effects can be significant, leading to structural weakening, safety hazards, and costly repairs or replacements. By remaining vigilant and implementing proactive measures, we can safeguard our metal assets against galvanic corrosion, ensuring they remain strong, reliable, and long-lasting for years to come.
To explore further on our blog content, click here.

Engineering Edge (Singapore) is your trusted fastener manufacturer with a legacy of delivering top-quality solutions. Our commitment to innovation and extensive Research and Development has led to exceptional fastening products, surpassing conventional designs. Our global customers benefit from dedicated support via our team of engineers and authorized distributors in over 20 countries worldwide.

Discover TAPPERMAN® Fasteners, the preferred choice of retail fasteners for builder's marts or hardware stores, offering versatile display and packaging solutions. Choose DYNO® Fasteners for quality-compliant structural solutions that guarantee peace of mind. For innovation-packed anti-corrosion premium fasteners, turn to CORROSHIELD® Fasteners. Extensive research has enabled us to design coatings tailored to various hostile environments.

All our products, TAPPERMAN®, DYNO®, and CORROSHIELD®,are tested and documented in accordance with the ISO 16228 Standard, ensuring excellence across our entire screw range. Stay connected with our latest innovations and product features by following us on Instagram, Facebook, LinkedIn, and YouTube. If you like to listen to interesting industrial how-tos and whys, listen to our podcast! Questions or inquiries? Reach out via our Contact Us page, and our experts will promptly assist you.